华子乐　研究员 

　　介孔与低维纳米材料课题组 

　　021-52412708

　　huazl@mail.sic.ac.cn

 

　　教育经历：
　　1992-1996，景德镇陶瓷学院材料工程系，硅酸盐工程专业，学士学位 
1996-1999，华南理工大学材料科学与工程学院，材料学专业，硕士学位 
1999-2002，中国科学院上海硅酸盐研究所，材料学专业，博士学位 

　　工作经历： 
2002-2005，中国科学院上海硅酸盐研究所，高性能陶瓷和超微结构国家重点实验室，助理研究员 
2004-2004，英国曼彻斯特大学，材料研究中心，访问学者 
2005-2013，中国科学院上海硅酸盐研究所，高性能陶瓷和超微结构国家重点实验室，副研究员 
2013-至今，中国科学院上海硅酸盐研究所，高性能陶瓷和超微结构国家重点实验室，研究员  

　　曾获得奖励、荣誉称号： 

　　中国科学院刘永龄一等奖学金（2002） 
第三届柳大纲优秀青年科技奖（2004） 
上海市自然科学一等奖（第四完成人，2008） 　　  

　　科研工作简介： 

　　(1) 多级孔材料研究

　　集成微孔、介孔与大孔结构特征与性能优势的多级结构孔材料吸引了材料化学、无机化学、催化化学等多领域研究人员的共同兴趣。合成的多级孔材料在分离、吸附、石油化工、精细化工等过程显示更好的使用性能，且突破了单一孔材料在某些过程中的使用限制，具有广阔的应用前景。在这一领域，我们的研究目标是通过合成新方法的设计，制备多种骨架组成、材料孔结构与表面性质可控的新型多级结构孔材料，开展合成多级孔材料的结构表征、新性能与应用基础研究。近年来，我们的主要研究进展包括设计了蒸气辅助晶化工艺(Chem.Eur.J.,2009,15,12949;ACS Catal.,2011,1,287...)与动力学控制自组装方法(Chem.Eur.J.,2011,17,14618;J.Catal,2013,299,20...)，以商品化试剂制备了高性能微-介孔多级结构材料；制备了介孔-大孔复合的氧化硅基和碳基块体材料(J.Sol-Gel Sci.Technol.,2009,50,22;Carbon,2014,66,547)等。 

　　  

　　(2) 介孔基纳米复合材料研究 

　　纳米材料的粒径、尺寸分布与分散性是决定材料性能的关键因素。具有高比表面积与丰富孔道结构的介孔材料是粒子尺寸可调、一致尺寸分布、高分散性的纳米复合材料制备的“天然微反应器”。目前，我们的研究工作集中于通过材料合成-组装新方法的设计，制备各种组成、各种结构的介孔材料；一步法或是合成后负载工艺制备介孔基纳米复合材料。我们的研究目标是将介孔基纳米复合材料应用于纳米医学、清洁能源(Chem.Commun.,2013,49,8006)、污染治理(J.Mater.Chem.A,2013,1,10218)、光学(J.Mater.Chem.,2009,19,7632)等领域。 

　　科研成果： 

1. Guiju Tao, Lingxia Zhang, Zile Hua, Yu Chen, Limin Guo, Jiamin Zhang, Zhu Shu, Jianhua Gao, Hangrong Chen, Wei Wu, Ziwei liu, Jianlin Shi*, “Highly efficient adsorbents based on hierarchically macro/mesoporous carbon monoliths with strong hydrophobicity”, Carbon, 2014, 66, 547-559. 
2. Guiju Tao, Zile Hua*, Zhe Gao, Yan Zhu, Yan Zhu, Yu Chen, Zhu Shu, Lingxia Zhang, Jianlin Shi*, “KF-loaded mesoporous Mg-Fe bi-metal oxides: high performance transesterification catalysts for biodiesel production”, Chemical Communications, 2013, 49, 8006-8008. 
3. Yan Zhu, Zile Hua, Yudian Song, Wei Wu, Xiaoxia Zhou, Jian Zhou, Jianlin Shi*, “Highly chemoselective esterification for the synthesis of monobutyl itaconate catalyzed by hierarchical porous zeolites”, Journal of Catalysis, 2013, 299, 20-29.  
4. Yudian Song, Zile Hua, Yan Zhu, Xiaoxia Zhou, Wei Wu, Linlin Zhang, Jianlin Shi*, “An in-situ carbonaceous mesoporous template for the synthesis of hierarchical ZSM-5 zeolites by one-pot steam assisted crystallization process”, Chemistry – An Asian Journal, 2012, 7, 2772-2776. 
5. Yudian Song, Zile Hua, Yan Zhu, Jian Zhou, Xiaoxia Zhou, Zhicheng Liu, Jianlin Shi*, “Solvent-free liquid phase tert-butylation of phenol over hierarchical ZSM-5 zeolites for the efficient production of 2,4-ditert-butylphenol”, Journal of Materials Chemistry, 2012, 22, 3327-3329. 
6. Zile Hua, Jian Zhou, Jianlin Shi*, “Recent advances in hierarchically structured zeolites: synthesis and material performances”, Chemical Communications, 2011, 47, 10536-10547.  
7. Yan Zhu, Zile Hua, Jian Zhou, Lijun Wang, Jinjin Zhao, Yun Gong, Wei Wu, Meiling Ruan, Jianlin Shi*, “Hierarchical mesoporous zeolites: direct self-assembly synthesis in a conventional surfactant solution route by kinetic control over zeolite seed formation”, Chemistry – A European Journal, 2011, 17, 14618-14627. 
8. Jian Zhou, Zile Hua, Zhicheng Liu, Wei Wu, Yan Zhu, Jianlin Shi*, “Direct synthetic strategy of mesoporous ZSM-5 zeolites by using conventional block copolymer templates and the improved catalytic properties”, ACS Catalysis, 2011, 1, 287-291. 
9. Jian Zhou, Zile Hua, Jianlin Shi*, Xiangzhi Cui, Zhengqing Ye, Fangming Cui, “Hierarchical mesoporous TS-1 zeolite: a highly active and extraordinarily stable catalyst for the selective oxidation of 2,3,6-trimethylphenol to trimethyl-p-benzoquinone”, Chemical Communications, 2010, 46, 4994-4996. 
10. Jian Zhou, Zile Hua, Jinjin Zhao, Zhe Gao, Shaozhong Zeng, Jianlin Shi*, “A micro/mesoporous aluminosilicate: key factors affecting framework crystallization during steam-assisted synthesis and its catalytic property”, Journal of Material Chemistry, 2010, 20, 6764-6771. 
11. Jian Zhou, Zile Hua, Jianlin Shi*, Qianjun He, Limin Guo, Meiling Ruan, “Synthesis of a hierarchical micro/mesoporous structure by steam-assisted post-crystallization”, Chemistry – A European Journal, 2009, 12949-12954. 
12. Zile Hua, Jianhua Gao, Wenbo Bu, Lingxia Zhang, Hangrong Chen, Jianlin Shi, “Hierarchically macro/mesoporous silica monoliths constructed with interconnecting micrometer-sized unit rods”, Journal of Sol-Gel Science and Technology, 2009, 50, 22-27. 
13. Zile Hua, Wenbo Bu, Yuxiang Lian, Hangrong Chen, Lei Li, Lingxia Zhang, Can Li, Jianlin Shi*, Post-grafting preparation of large-pore mesoporous materials with localized high content titanium doping, Journal of Materials Chemistry, 2005, 15, 661-665. 
14. Jianlin Shi, Zile Hua, Lingxia Zhang, “Nanocomposites from ordered mesoporous materials”, Journal of Materials Chemistry, 2004, 14(5), 795-806. 
15. Zile Hua, Jianlin Shi*, Lingxia Zhang, Meiling Ruan, Jina Yan，Formation of nano- sized TiO2 in mesoporous silica thin films (MSTFs)，Advanced Materials，2002, 14(11), 830~833; 
16. Zile Hua, Jianlin Shi*, Lingxia Zhang, Meiling Ruan, Xueguo Zhao, Acid-prepared mesostructures modified with TiO2 by template-titanium tetrabutoxide displacement process, Journal of Materials Chemistry, 2001, 11, 3130~3134. 

　　详细介绍： 

　　http://www.sic.cas.cn/JLShi/