崔香枝，研究员，博士生导师 

　　介孔与低维纳米材料课题组 

　　021-52412018 

　　cuixz@mail.sic.ac.cn 

　　  

　　教育经历：  

　　1999—2003，郑州大学，材料科学与工程，学士学位  

　　2003—2006，郑州大学，无机非金属材料，硕士学位  

　　2006—2009，中国科学院上海硅酸盐研究所，材料物理化学，博士学位 

 

　　工作经历：  

　　2009—至今，中国科学院上海硅酸盐研究所，高性能陶瓷和超微结构国家重点实验室，助理研究员、副研究员、研究员  

　　2013—2014，美国科罗拉多矿业大学，访问学者 

　　  

　　曾获得奖励、荣誉称号： 

　　上海市院士专家工作站“引智创新成果”50佳（2021）

　　中科院上海硅酸盐研究所“巾帼建功”先进个人（2018-2019）

　　中科院上海硅酸盐研究所优秀青年（2018）

　　入选为中国科学院青年创新促进会会员（2012）  

　　中科院 上海硅酸盐研究所所“优秀个人”（2011）  

　　中科院“优秀博士学位论文、院长奖获得者科研启动专项资金”的资助（2010）  

　　中科院 “百篇优秀博士论文”（2010）  

　　上海市研究生优秀成果奖（2010）  

　　中科院“院长奖学金”优秀奖（2009） 

　　  

　　科研工作简介： 

　　瞄准双碳国家战略目标，主要进行氢/小分子燃料电池、电解水制氢、绿色电合成相关的前沿应用研究，针对氢/小分子燃料电池、电解水制氢和绿色电合成中的低效率、高过电势和高成本的瓶颈问题，开展了关键电催化反应中催化剂材料的设计制备和核心膜电极部件的构建研究，探讨材料组成与电催化性能间的构效关系，阐明相应的电催化机制。实现了非Pt催化剂达到商用贵金属催化剂92%的氢燃料电池输出功率，利用CCM技术实现不同尺寸膜电极10mm×10mm、20mm×20mm、50mm×50mm、1000mm×300mm的制备，并进行电堆的压制和组装。

　　作为负责人主持承担了国家自然科学基金（青年/面上）、上海市自然科学基金（面上/探索/国合）、中科院创新项目、企业横向等项目。

　　在Angew. Chem. Int. Ed.、Adv. Mater.、Energy Environ. Sci. 、Prog. Mater. Sci等期刊上发表论文80余篇，H因子28；出版专著一部；获得15项国家发明专利授权。中国能源学会专委会委员，上海市汽车零部件协会燃料电池产业专家。

　　  

　　科研成果：  

1.质子交换膜燃料电池（PEMFC）关键电催化材料

　　针对PEMFC中阳极氢气氧化反应（HOR）和阴极氧还原反应（ORR）所存在的关键科学问题，研究并制备出具有高效HOR、ORR的非铂电催化剂材料，相关工作发表在Angew. Chem. Int. Ed.、Adv. Mater.、Energy Storage Mater.、Prog. Mater. Sci.等期刊上。

Nano Res. 2021, 14, 2441.

Chem. Eng. J. 2021, 421, 129430 

J. Mater. Chem. A, 2022, 10, 622. 

Angew. Chem. Int. Ed. 2022, 61,e202116290.

Adv. Mater. 2021, 2100997

Energy Storage Mater. 2021, 37, 274-282.

Prog. Mater. Sci., 2022, 128, 100964

2.构建小分子燃料电池关键电催化材料

　　针对便携式液体燃料电池中小分子燃料氧化存在的关键科学问题，研究出具有高效的甲醇氧化反应（MOR）、肼氧化反应（HzOR）催化性能的电催化材料，相关工作发表在Energy Environ. Sci.、J. Mater. Chem. A等期刊上。 

Energy Environ. Sci., 2015, 8, 1261-1266

3.电解水制氢

　　针对电解水制氢中存在的大电流密度下的阴极氢析出反应（HER）活性低、阳极水氧化反应（OER）动力学缓慢造成的槽压高、能耗大的关键科学问题，采用创新材料设计策略获得广pH值的电解水制氢性能；采用耦合阳极电催化氧化以降低槽压，节约能耗；构建多功能催化剂，实现自供电—联产氢气。相关工作发表在Angew. Chem.Int. Ed.、Nano Energy、Appl. Catal.B Environ.等期刊上。

Nano Energy 2021, 80, 105531

Appl Catal B Environ., 2022, 308, 121229.

Appl Catal B Environ., 2021, 297, 120474.

Appl Catal B Environ., 2022, 304, 121008.

Angew. Chem.Int. Ed., 2022, DOI: 10.1002/anie.202207226

 

4.绿色电合成

　　耦合绿电（风、光、水）的清洁能源，采用电化学手段合成NH₃（氮气还原反应，NRR）、合成甲酸等，针对该电化学合成中存在的转化效率低、法拉第效率低的关键问题，设计了纳米复合电催化材料，研究了其中的电催化机制、动力学。相关工作发表在Chem Catal.等期刊上。

Chem Catal., 2022, 2, 358

科研成果（2017年至今）：

(1)   Chang Chena, Zhengqian Fu, Fenggang Qia, Yafeng Chen, Ge Meng, Ziwei Chang, Fantao Kong, Libo Zhua, Han Tian, Haitao Huang, Xiangzhi Cui*, and Jianlin Shi*. Fe²⁺/Fe³⁺ Cycling for Coupling Self-powered Hydrogen Evolution and Preparations of Electrode Catalysts, Angew. Chem.Int. Ed., 2022, DOI: 10.1002/anie.202207226.

(2)   Penghao Ji, Shenyan Zhang, Peilei Liu, Xi Li, Weichao Bao, Xiangzhi Cui*, Minfeng Huo*, Jianlin Shi. Modulation of Mitochondrial Electron Transport Chain by Pyroptosis Nanoagonists for Photoresponsive Tumor Destruction, Nano Today 2022, 44, 101511.

(3)   Yifan Huang, Fantao Kong,* Han Tian, Fenglai Pei, Yafeng Chen, Ge Meng, Ziwei Chang, Chang Chen, Xiangzhi Cui,* and Jianlin Shi. Ultrauniformly Dispersed Cu Nanoparticles Embedded in N-Doped Carbon as a Robust Oxygen Electrocatalyst, ACS Sustainable Chem. Eng. 2022, 10, 6370-6381.

(4)   Yongxia^#, XiangzhiCui^# (共一), Jinqiang Zhang,* Jinli Qiao,* Haitao Huang, Jianlin Shi, Guoxiu Wang*. Advances of atomically dispersed catalysts from single-atom to clusters in energy storage and conversion applications, Prog. Mater. Sci., 2022, 128, 100964.

(5)   FantaoKong, XiangzhiCui,* YifanHuang, HeliangYao, YafengChen, HanTian, Ge Meng, ChangChen, ZiweiChang, and JianlinShi*. N-Doped Carbon Electrocatalyst: Marked ORR Activity in Acidic Media without the Contribution from Metal Sites? Angew. Chem.Int. Ed., 2022, 61,e202116290.

(6)   Xiangzhi Cui*, Introducing hydrogen bonds in RuO₂ boosts acidic OER activity and stability, Chem Catal., 2022, 2, 431-433.

(7)   Ge Meng, Heliang Yao, Han Tian, Fantao Kong, Xiangzhi Cui,* Shaowen Cao, Yafeng Chen, Ziwei Chang, Chang Chen, Jianlin Shi,* Electrochemical-reconstructed WC/WO₂-WO₃ heterostructure as a highly efficient hydrogen oxidation electrocatalyst, J. Mater. Chem. A, 2022, 10, 622.

(8)   Chang Chen, Han Tian, Zhengqian Fu, Xiangzhi Cui,* Fantao Kong, Ge Meng,Yafeng Chen , Fenggang Qi , Ziwei Chang, Libo Zhu, Haitao Huang, Bao Yu Xia, Jianlin Shi.* Pt NPs-loaded siloxene nanosheets for hydrogen co-evolutions from Zn-H₂O fuel cells-powered water-splitting, Appl. Catal. B Environ., 2022, 304, 121008.

(9)   Ziwei Chang, Fantao Kong, Min Wang, Shuhe Han, Xiangzhi Cui,* Han Tian, Yafeng Chen, Ge Meng, Chang Chen, Yang Liu, Yifan Huang, and Jianlin Shi1** Efficient Ammonia Electrosynthesis by Coupling to Concurrent Methanol Oxidation, Chem Catal., 2022, 2, 358-371.

(10)Lingxin Peng, Liang Su, Xu Yu, Rongyan Wang1, Xiangzhi Cui*, Han Tian, Shaowen Cao, Bao Yu Xia*, Jianlin Shi*, Electron redistribution of ruthenium-tungsten oxides Mott-Schottky heterojunction for enhanced hydrogen evolution, Appl. Catal. B Environ., 2022, 308, 121229.

(11)Fenglai Pei, Meixin Chen, Fantao Kong*, Yifan Huang, Xiangzhi Cui*, In-situ coupling FeN nanocrystals  with Fe/Fe₃C nanoparticles to N-doped carbon nanosheets for efficient oxygen electrocatalysis, Appl. Surf. Sci., 2022, 587, 152922.

(12)Yongxia Wang^#, Xiangzhi Cui^# (共一), Luwei Peng, Lulu Li, Jinli Qiao *, Haitao Huang, Jianlin Shi*, Metal–Nitrogen–Carbon Catalysts of Specifically Coordinated Configurations toward Typical Electrochemical Redox Reactions, Adv. Mater. 2021, 2100997.

(13)Han Tian, Xiangzhi Cui*, Hongliang Dong, Ge Meng, Fantao Kong, Yafeng Chen, Lingxin Peng, Chang Chen, Ziwei Chang, Jianlin Shi*. Engineering single MnN4 atomic active sites on polydopamine-modified helical carbon tubes towards efficient oxygen reduction, Energy Storage Mater. 2021, 37, 274-282.

(14) Ge Meng, Han Tian, Lingxin Peng, Zhonghua Ma, Yafeng Chen, Chang Chen, Ziwei Chang, Xiangzhi Cui*, Jianlin Shi* , Ru to W electron donation for boosted HER from acidic to alkaline on Ru/WNO sponges, Nano Energy 2021, 80, 105531.

(15) Ge Meng, Ziwei Chang, Xiangzhi Cui*, Han Tian, Zhonghua Ma, Lingxin Peng, Yafeng Chen, Chang Chen, Jianlin Shi*, SnO₂/CeO₂ nanoparticle-decorated mesoporous ZSM-5 as bifunctional electrocatalyst for HOR and ORR, Chem. Eng. J. 2021,417,127913.

(16)Lingxin Peng, Han Tian, Xiangzhi Cui*, Liang Su, Ge Meng, Zhonghua Ma, Shaowen Cao, Jianlin Shi*. Dual synergetic catalytic effects boost hydrogen electric oxidation performance of Pd/W₁₈O₄₉, Nano Res. 2021,14(7):2441-2450.

(17) Han Tian, Xiangzhi Cui*, Jianlin Shi*. Emerging electrocatalysts for PEMFCs applications: Tungsten oxide as an example, Chem. Eng. J. 2021, 421(1):129430.

(18) Yafeng Chen, Heliang Yao, Fantao Kong, Han Tian, Ge Meng, Shuze Wang, Xinping Mao, Xaingzhi Cui*, Xinmei Hou*, Jianlin Shi. V₂C Mxene Synergistically Coupling FeNi LDH Nanosheets for Boosting Oxygen Evolution Reaction. Appl. Catal. B Environ., 2021, 297, 120474.

(19) Yafeng Chen, Guimin Jiang, Xiangzhi Cui*, Zuotai Zhang*, Xinmei Hou*. Fabrication of Pd/CeO₂ nanocubes as highly efficient catalysts for degradation of formaldehyde at room temperature, Catalysis Science & Technology, 2021, 11(20):6732-6741.

(20) Zhonghua Ma, Chang Chen, Xiangzhi Cui*, Liming Zeng, Lianjun Wang*, Wan Jiang, Jianlin Shi. Hydrogen Evolution/Oxidation Electrocatalysts by the Self-Activation of Amorphous Platinum, ACS Appl. Mater Inter., 2021, 13(37):44224-44233.

(21) Han Tian, Liming Zeng, Yifan Huang, Zhonghua Ma, Ge Meng, Lingxin Peng, Chang Chen, Xiangzhi Cui*, Jianlin Shi*. In Situ Electrochemical Mn(III)/Mn(IV) Generation of Mn(II)O Electrocatalysts for High-Performance Oxygen Reduction, Nano-Micro Lett. 2020, 12,161.

(22) Zhonghua Ma, Han Tian, Ge Meng, Lingxin Peng, Yafeng Chen, Chang Chen, Ziwei Chang, Xiangzhi Cui*, Lianjun Wang*, Wan Jiang*, Jianlin Shi. Size effects of platinum particles@CNT on HER and ORR performance, Sci.China Mater. 2020, 63(12):2517-2529.

(23) Han Tian, Xiangzhi Cui*, Liming Zeng, Liang Su, Yiling Song, Jianlin Shi*.  Oxygen vacancy-assisted hydrogen evolution reaction of the Pt/WO₃ electrocatalyst, J. Mater. Chem. A, 2019, 7, 6285-6293.

(24) Liang Su, Xiangzhi Cui*, Ting He, Liming Zeng, Han Tian, Yiling Song, Kai Qi, Bao Yu Xia*, Surface reconstruction of cobalt phosphide nanosheets by electrochemical activation for enhanced hydrogen evolution in alkaline solution, Chem. Sci., 2019, 10, 2019-2024.

(25) Yiling Song, Xiaohua Zhang, Xiangzhi Cui*, Jianlin Shi*. The ORR kinetics of ZIF-derived Fe-N-C electrocatalysts, J Catal., 2019, 372, 174-181.

(26) Xiangzhi Cui*, Lu Meng, Xiaohua Zhang, Xingang Wang, Jianlin Shi. Heterogeneous atoms-doped titanium carbide as a precious metal free electrocatalyst for oxygen reduction reaction, Electrochimica Acta 2019, 295, 384-392.

(27) Liming Zeng, Xiangzhi Cui*, Jianlin Shi*. A facile strategy for ultra small Pt NPs being partially embedded in N-doped carbon nanosheet structure for efficient electrocatalysis. Sci China Mater 2018, 61(12): 1557-1566.

(28) Xiaohua Zhang, Ping Lu, Chen Zhang, Xiangzhi Cui *, Yingfeng Xu, Haiyun Qu, Jianlin Shi*. Towards understanding ORR activity and electron-transfer pathway of M-Nx/C electro-catalyst in acidic media, J. Catal., 2017, 356: 229-236.

(29)  Liming Zeng, Xiangzhi Cui*, Lisong Chen, Ting Ye, Weimin Huang, Ruguang Ma, Xiaohua Zhang, Jianlin Shi*, Non-noble bimetallic alloy encased in nitrogen-doped nanotubes as ahighly active and durable electrocatalyst for oxygen reduction reaction, Carbon, 2017, 114: 347-355.